Audio Source: Hadeeth # 11 from Umdatul Ahkaam – Book of Purification – Dr. Saleh as Saleh [Audio|En]
It is recommended for the person who wants to enter the toilet to say:
بِسْمِ الله ) اللَّهُمَّ إِنِّي أَعُوْذُ بِكَ مِنَ الْخُبُثِ وَالْخَبَائِثِ)
(Allaahummaa innee a`oodhu bika minal-khubuthi wal-khabaa·ith)
(With the name of Allaah),
(O Allaah! I seek Your refuge from male and female devils).
This is because of the hadeeth of `Alee -radiyallaahu `anhu- that the Prophet (صلّى الله عليه وسلّم ) said:
<<The screen between the jinn and the private-parts of the descendants of Aadam, when one of you enters the toilet, is that he says:‘Bismillaah’ (with the name of Allaah).>> 
And because of the hadeeth of Anas -radiyallaahu `anhu- who said: “When Allaah’s Messenger (صلّى الله عليه وسلّم ) went to the toilet he used to say:
اللَّهُمَّ إِنِّي أَعُوْذُ بِكَ مِنَ الْخُبُثِ وَالْخَبَائِثِ
‘Allaahummaa innee a`oodhu bika minal-khubuthi wal-khabaa·ith’
(O Allaah! I seek Your refuge from male and female devils).” 
 Saheeh: Saheehul-Jaami` (3611); at-Tirmidhee (2/59/606)-and this is his wording; Ibn Maajah (1/109/297)…
 Agreed upon: al-Bukhaaree (1/242/142), Muslim (1/283/375), Aboo Daawood (1/21/4), Ibn Maajah (1/109/298), at-Tirmidhee (1/76), an-Nasaa·ee (1/20)
[Translation taken from: Toilet Manners (Aadaabul-Khalaa) – Dawood Burbank]
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